Heather.
Heather was a strategist, and her better-than-you attitude made you love to hate her.She wasn't really that great at challenges in themselves, but won through her intelligence. She was something of a bully, but she got her comeuppance. Every episode, one way or another. I cannot remember her ever actually cheating.
Courtney was just a bossy, inconsiderate bully in season 1. She was pretty human in ability. Now that she's the villain, she almost never gets any comeuppance(what she gets is horribly underpowered, too), she sudden developed mad physical skills out of the blue(while Heather used her brain), and now she's a "master manipulator" too(this I can blame on her competitors being morons, however).
Hmm. Seldom gets any comeuppance, suddenly gained superb physical abilities, just happens to be great at singing, supposedly very attractive with several boys falling for her.
The ONLY things saving her from being a Jerk Sue(See link below) is the fact that we really know she'll fall and fall hard, and that the creators are obviously intending her to be villainous.
Heather was the intelligent, scheming type of villain we love to hate. Courtney's the brawny borderline Jerk Sue that we just find aggravating.